I'm still really new at this EV training stuff. I have a question if you could help me. I've heard that in Gen 5 you can EV train even level 100s. How is that possible? Can you explain that thoroughly to me? Concrete example: I have a level 90 Hydreigon that I want to EV train in Sp.Att and lower his Sp.Def. How do I do that? How do I re-organise his EVs step by step?
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To answer your questions - yes Pokémon can be EV trained when they hit level 100. They changed the mechanics *shrug*. Just safe to say it works as normal as if its at any other level.
To reduce EVs, you need to get berries only found on Dream World found here: http://en.pokemon-gl.com/ They're rare berries, and it'll take a while to get enough of them.
To train in Special Attack, battling Litwick / Elegyms in Celestial Tower is the best spot. They give 1 EV each, but with a Power Lens thats 5 EVs a battle - you only need 25 battles to hit 250, and attach a Macho Brace for the extra 2 EVs to reach 252, the highest usuable number of EVs. You can hit 255, but that wastes EVs as it won't affect the stat.